First Punjab Chief Minister
Iftikhar Hussain is the correct answer. 

Sindh's first chief minister 
Ayub Khoro is the correct answer. 

Khyber Pakhtunkhwa's First Chief Minister 
Dr. Khan Sahib is the correct answer. 

Balochistan's First Chief Minister 
Sardar Atta Ullah Mengal is the correct answer. 

First Punjab Governor 
Sir Francis Moody is the correct answer.

Punjab's First Muslim Governor 
Nishtar Sardar Abdur Rab is the correct answer.

Sindh's First Governor 
Hidayatullah Ghulam Hussain is the correct answer.

Khyber Pakhtunkhwa's First Governor (NWFP) 
Sir George Cunningham is the correct answer.

Khyber Pakhtunkhwa's First Muslim Governor 
Mohammad Khurshid Sahibzada is the correct answer.

Balochistan's First Governor 
Gen. Riaz Hussain is the correct answer.

Gilgit-Baltistan First Governor:
Shamma Khalid is the correct answer.

First Army Commander in Chief
Gen.Frank Meservy is the correct answer.

Muslim Army First Commander-in-Chief 
G.M. Ayub Khan is the correct answer.

First Air Force Commander in Chief 
Marshal Allan Perry Keene is the correct answer.